Selective etching of epitaxial MnAs films on GaAs(001): Influence of structure and strain

Mohanty J, Takagaki Y, Hesjedal T, Däweritz L, Ploog KH

Strain in epitaxial MnAs thin films on GaAs(001) substrates plays an important role in the coupled magnetostructural phase transition. As a result of strain, the phase transition from the ferromagnetic α phase to the paramagnetic Β phase proceeds over a wide temperature range and the coexisting phases form a periodic stripe array. Employing suitable wet chemical etchants, the two MnAs phases can be etched selectively. Perpendicular to the α-Β -stripe structure, the built-up strain relaxes in the course of the etching process by the formation of cracks. The combination of both strain relaxation mechanisms allows for the defined patterning of two-dimensional arrays of nanomagnets. Through micromagnetic investigations, it is possible to identify the location of α - and Β-MnAs which helps to clarify two major aspects of the etching process. First, it is possible to determine the etch rates of α - and Β-MnAs and follow the complex interplay of strain and phase composition during the etching process. Second, as strain reflects itself in a shifted phase-transition temperature, temperature-dependent micromagnetic studies allow to determine the strain environment of the cracks. © 2005 American Institute of Physics.